Recovering in-demand metals for new electronics—researchers find industrial-strength adsorbents soak up lanthanum

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Adsorption of La(III) by various adsorbents: (a) Percentage removal after 7 h of adsorption: 1. Dowex 50W-X8, 2. Amberchrom50WX4, 3. Amberlyst 15, 4. Amberchrom 50WX2; (b) Amount adsorbed vs. time (pH = 5.5, T = 25.0 °C). X-ray images of resins: (c) Dowex 50W-X8 particle, (d) zoomed-in image of a Dowex-8X particle' surface; (e) Amberchrom 50WX4 particles, (f) zoomed-in image of Amberchrom 50WX4; (g) Amberlyst particle, (h) zoomed-in image of Amberlyst; (i) Amberchrom 50WX2 particle, (j) zoomed-in image of Amberchrom 50WX2; (k) Majority particle sizes of the adsorbents, (l) Measured particle size distribution of Dowex 50W-X8; (m) SEM image of fresh Dowex 50W-X8 and (n) EDS spectrum of the resin; (o) SEM image of Dowex 50W-X8 after 7 h of adsorption and (p) EDS spectrum of the resin. Credit: Inorganics (2024). DOI: 10.3390/inorganics12090255

Nearly all technology today—from cellphones to computers to MRI scanners—contains rare earth elements (REEs). The global market for REEs is predicted to reach $6.2 billion (USD) this year and $16.1 billion (USD) by 2034.

High concentrations of one particular REE—lanthanum—are often found in mine tailings. Runoff from this waste can make its way into nearby bodies of water where it poses a risk to human health and the environment. As a result, researchers are on the hunt for ways to recover the material.

Michael Chan, working under the supervision of Dr. Huu Doan in the Department of Chemical Engineering at Toronto Metropolitan University (TMU), recently discovered that industrial-strength chemical adsorbents can be used to "soak up" lanthanum from that mine waste. The research is published in the journal Inorganics.

"These 'fancy sponges' are about the size of a grain of salt," says Chan, who is completing his Masters degree at TMU. Working in a lab, Chan and his colleagues found that the metal ions present in a sample of contaminated water trade places with the hydrogen ions present on the surface of adsorbent.

When they filtered the adsorbent out of the water, they were left with cleaner water and recovered lanthanum that could be reformed and reused in new electronics.

Recovering in-demand metals for new electronics. Credit: Canadian Light Source

The team used a scanning electron microscope at TMU to better understand the ion exchange process, then used the Canadian Light Source at the University of Saskatchewan to get even more detailed images and to confirm their findings.

"The exciting part about these findings is that this is something that we can do now, today," says Chan. "We can use what we have. We can really give it a shot and apply it to real-life situations and industry."

Chan and his team collaborated with Dr. Trong Dang-Vu from SNF Canada, a company specializing in water treatment solutions.

"They were able to guide us in terms of what industry is looking for," says Chan. "They also provided us with tailings samples from mines, so in further research we'll see if we can use those samples and see just how effective this approach really is."

More information: Michael Chan et al, An Investigation of Lanthanum Recovery from an Aqueous Solution by Adsorption (Ion Exchange), Inorganics (2024). DOI: 10.3390/inorganics12090255

Provided by Canadian Light Source